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Application Notes
Our database of GPC/SEC application notes explain the use of concentration, viscometer and light scattering detectors to obtain a distribution of absolute molecular weight, size and intrinsic viscosity, as well as information on conformation, aggregation, branching and copolymer composition.
 
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DSV Theory
Dilute Solution Viscosity Theory - Automation and Applications

DSV Automation

Viscotek developed the Model Y501 Relative Viscometer several years ago for DSV measurement. It provides fast, precise, automated measurements and has become the world standard, displacing traditional glass tube viscometers. The bottleneck on DSV productivity then became the sample preparation.
Robotics sample prep is an obvious solution and has been shown to improve productivity, precision, and safety in several laboratories. However, robotics has drawbacks:

  • It requires considerable laboratory space.
  • Specialized training needed for maintenance of robotics system.
  • It is very expensive.

Automated Relative Viscometer (ARV) System

Viscotek developed the ARV system in response to the need for automation of the sample preparation as well as the viscosity measurement. Main components of the system:

  • Analytical Balance
  • Syringe Dispensers (2)
    • Solution preparation, sample loading
  • Vortex HT Autosampler
    • Stirs, dissolves and loads sample
  • Y501 Relative Viscometer
    • Heated transfer line for polyolefin applications
    • Water Re-circulator cools solution to RT for PET, PVC.
    • Degasser (Aqueous and volatile organic solvents)
  • Data Station with ARV Software for instrument control

The ARV allows the operator to place an approximate amount of sample into the sample vial, letting the balance record the weight accurately. Then the vial is capped and moved to the Vortex autosampler where automatically, the appropriate amount of solvent is added, selected temperature and proper stirring speed applied. After the stirring is completed, the stirring stops and the viscometer takes in the sample from the vial for testing, results are calculated and reported on the computer. The operator reports the results and discards the vials, ready for the next batch of samples.

Summary of Practical ARV Advantages

  • Faster, easier analysis than conventional glass tubes
  • Minimized solvent exposure to operators (Safety)
  • Removes temperature issue
  • More accurate
    • Removes operator subjectivity
    • High precision
      • Typically better than 0.2% RSD on the calculated viscosity function
      • Overall precision mostly limited by sample heterogeneity
  • Better Precision
  • Easy to change solvent (15 min)
  • Less solvent use
  • Various levels of automation available

Applications

Below are some common viscosity applications. Other applications are also suitable for the ARV.

  • PET in OCP/Phenol or Ph/TCE
  • PVC in THF or Cyclohexanone
  • Nylon/Polyesters in Cresol or HFIP
  • PE/PP in TCB or Decline
  • Delrin in HFIP
  • Nylon in Formic Acid
  • Polycarbonate in Dichloromethane
  • Starches in DMSO
Complete Gel Permeation Chromatography (GPC) / Size Exclusion Chromatography (SEC) systems for the characterization of natural and synthetic polymers, proteins, conjugates and excipients. Integrated Triple and Tetra Detector Arrays (TDAs) featuring Low Angle Light Scattering (LALS) detectors, four capillary differential viscometer detectors, refractometers and UV/VIS detectors; in a single experiment, obtain absolute molecular weight, molecular size, intrinsic viscosity, conformation, branching, aggregation and copolymer composition. Flow Injection Polymer Analysis (FIPA) for fast, accurate and precise average molecular weight, size and intrinsic viscosity in routine QA/QC and process control. Automated Dilute Solution Viscosity (DSV) systems provide relative, inherent, and intrinsic viscosity.